By Hill Jr C.G.
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Additional info for An introduction to chemical engineering kinetics & reactor design
3) This function is also commonly called the heat content. e. for p = const or dp = 0, dH = dU + pdV and hence, according to eqn. (2), dQ = dH. e. thermodynamically speaking into a balance region, and removed again from it after some transformation or work has been done. These flows of material supply not only their internal energy 17Λ (Fig. 1), but also the associated flow work/? a F a . On the other hand t A detailed account of the theory simply outlined here is given, for example, in Zemansky [ThlO], chap.
2), h = 4-905*2. 4) But this equation is only valid for A in m and t in s. To use it for other units, another figure must be substituted for the numerical constant 4-905, thus, for the units of the CGS system, h = 490·5ί2. 5) Unlike in the case of eqn. (2), only the corresponding numerical values can bo introduced into this equation because introduction of the quantities would give 19-62m = 4-905 x (2s)2 or the dimensional equation Im = s2. Equa tions of the type of (4) and (5), in which the right- and left-hand sides do not agree in their dimensions—the different terms depend on various dimensions— are thus called dimensional equations.
That a two-atom molecule actually rotates round the two axes perpendicular to the line connecting the atoms (cf. 5). In order to be independent of measuring systems it is often advantageous— especially in tables, and also in Fig. 1—to give, not the specific heats Cp or CV9 but the dimensionless quantities CJR, CJR or CPICp0. 11 1. What heat flow is required to heat 1000 kg/h of air at p= 1 atm from 600° to 2000°C, and how great is the mean specific heat in this temperature interval? 3 3 Data: c.
An introduction to chemical engineering kinetics & reactor design by Hill Jr C.G.